Minor acid burns can often be effectively treated at home 2. Like most caustic chemicals, when acids contact the skin, they cause damage in the form of a burn. Formic acid has a large heat of solution; the combined heat of neutralization and dilution will lead to thermal burns. It is classified as a weak acid since it only partially dissociates in solution, but concentrated acetic acid is corrosive and can attack the skin. Systemic toxicity developed in a 3-year-old girl burned by formic acid over 35% of her total body surface area. 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H226 Flammable liquid and vapour. H302 Harmful if swallowed. Formic Acid is an organic acid. Formic acid skin burns resulting in systemic toxicity. Both positive and negative results were noted in various mutagenicity studies (acidic experimental conditions were indicated in most cases of positive mutagenicity). Skin Corr. Formic Acid Livestock June 1, 2011 Compiled by ICF International for the USDA National Organic Program Page 1 of 12 1 2 ... 38 tissue and is known to irritate the mucous membranes and blister the skin (NOAA, 2011). AMINIC ACID, FORMIC ACID, FORMYLIC ACID, HYDROGEN CARBOXYLIC ACID, and METHANOIC ACID Page 1 of 7 Formic Acid 64 -18 6 MATERIAL SAFETY DATA SHEET SDS/MSDS. Acid burns frequently occur in the home or at work 2. Skin corrosion (Category 1A), H314 For the full text of the H-Statements mentioned in this Section, see Section 16. 3: Signal Word: Danger: Pictograms: GHS02 GHS05 GHS06 GHS07: Hazards: H226 Flammable liquid and vapour. It is important to treat acid burns correctly because otherwise, the chemicals can continue to damage the skin after the first contact, explains the Merck Manual. Immediately treat affected areas with copious amounts of water. 1A Acute Tox. P233 Keep container tightly closed. Workers exposed to formic acid in a textile plant complained of nausea at an average formic acid concentration of 15 ppm [NLM 1992]. It consists of a methyl group attached to a carboxyl group. Precautions: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. H302 Harmful if swallowed. Formic acid is dangerously irritating to the skin, eyes, and mucous membranes and may also be toxic to the kidneys. Acetic acid is the second simplest carboxylic acid (after formic acid). H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. Contact with the skin will cause immediate blistering. Do not use dilute base solutions as a first treatment. Author information: (1)Department of Emergency Medicine, University of California, San Diego, USA. Chan TC(1), Williams SR, Clark RF. No smoking. It is somewhat 39 soluble in hydrocarbons and most organic solvents, and forms a homogenous mixture (miscible) with 40 water. 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